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Ah, that sounds amazing! (I know who I'm contacting for advice when we finally book a tour of the wine country! My husband and I have been wanting to visit for a LOOOONG time.)
Doing a wine tour is a great idea, there are lots of areas to choose from. If you want to cover a large area and see lots of landscape, I would visit the winerys around San Louis Obispo and Paso Robles. The movie Sideways features this area.
If you like doing active stuff, the Napa area has winerys close together and you can bike or even run to several in a day. Napa is absolutely gorgeous country though.