I often masturbate in the morning, not long after I get up. Some mornings, my wife and I have sex; a lot of other mornings, she's up and getting ready for work long before I wake up. On those mornings when we don't connect, I often put my morning wood to good solo use.
If I don't hit it first thing, I'll usually take some me time at lunch, or maybe take a mid-morning or mid-afternoon break. The ability to do this has been my #1 unexpected benefit of working from home.